Why do I have to report zinc compounds when I only release a few pounds a year to the environment?
When zinc compounds are manufactured in quantities greater than 25,000 pounds per year, or otherwise used in quantities greater than 10,000 pounds per year, the Form R must be completed, regardless of how much of the zinc compounds are released to the environment.
A hot-dip galvanizing facility has many reports to file each year identifying the hazardous materials on site, used in the process, or stored at the facility. The report requiring zinc compounds to be reported is the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), Superfund Amendment and Reauthorization Act of 1990 (SARA), Title III Section 313, Toxic Release Inventory. This Section of CERCLA requires reporting if the chemicals used at the facility is on the 313 list and the facility manufactures, processes or otherwise uses the chemical above the reporting threshold quantity. Once the reporting threshold is met, the report must be filed. If you only release a few pounds a year to the environment, then you have achieved the goal of using a listed chemical material without significant impact to the environment. However, if the total pounds of zinc compounds manufactured, processed or otherwise used at your facility exceeds the reporting thresholds you still have to complete and submit the Form R by July 1 each year. The AGA has developed a very detailed guidance document which focuses on completing the Toxic Release Inventory Form R. I have paraphrased a few sections here to assist you with the decision and calculations necessary to document your position. Please refer to the full text of the AGA guidance document for example calculations and guidance on the release estimates.
SARA III, Section 313 defines manufacturing and otherwise used as the following:
- Manufacturing is to produce, prepare, compound or import a reportable chemical. Manufacture also includes coincidental manufacture or production of an EPCRAi Section 313 chemical (e.g. by-products or impurity) because of the manufacture, processing, otherwise use, or treatment of other chemical substances.1 The de minimis rule applies to the coincidental production of an impurity but not to by-products.
- An impurity is not separated and remains primarily in the mixture or trade name product with another chemical. A by-product is separated from the other chemical substance or mixture and is further processed or disposed of. EPCRA Section 313 chemicals produced as a result of waste management are also considered by-products. Otherwise used is any use including a chemical in a mixture or trade name product or waste that is not covered by the terms of manufacture or process. Otherwise, use activities can also be termed non-incorporative activities. Otherwise, use activities can be as a chemical processing aid, manufacturing aid, and ancillary or other use. An EPCRA Section 313 chemical that is added to a reaction mixture to aid in the manufacture or synthesis of another chemical substance but is not intended to remain in or become part of the product or product mixture is otherwise used as a chemical processing aid. An EPCRA Section 313 chemical that aids the manufacturing process but does not become part of the resulting product and is not added to the reaction mixture during the manufacture or synthesis of another chemical substance is otherwise used as a manufacturing aid.
- The manufacturing and processing activities have a reporting threshold of 25,000 lbs. The otherwise use activity has a reporting threshold of 10,000 lbs. Galvanizers chemicals are otherwise used in the galvanizing process with only chromium compounds being processed, ammonia being manufactured and otherwise used and zinc compounds being otherwise used and manufactured as a by-product. Ammonia is manufactured as it is processed for on-site use and is otherwise used as a manufacturing aid. Chromium compounds are processed as a formulation component. Hydrochloric and sulfuric acid aerosols are otherwise used as ancillary or otherwise use. Lead is otherwise used as a chemical processing aid. Zinc in the form of fume or dust is otherwise used as ancillary or otherwise use. Zinc compounds are manufactured as by-products and otherwise used as a chemical processing aid.i
Once either threshold quantity for zinc compounds (manufactured or otherwise used is met then a Release Form (Form R), must be completed for the total amount of zinc compounds at the facility. Zinc compounds are otherwise used in the galvanizing process in the flux bath as zinc chloride and are manufactured as by-products in the dry skimmings and stripping tank. In determining the amount of zinc chloride otherwise used in a year, the total amount of flux added and the percent of zinc chloride in the flux should be known. Multiplying these together will give the total amount of zinc chloride otherwise used in a year.
Lbs. ZnCl2/yr = (Amount of Flux added lbs./yr) x (% ZnCl2 in Flux/100)
Zinc compounds are manufactured as by-products at the galvanizing kettle and at the stripping tank. To determine the total amount of zinc compounds manufactured as by-products, each of the two areas are taken separately and then totaled together. To determine the amount of by-products manufactured as zinc oxide at the galvanizing kettle, the first step is to determine the total amount of dry skimmings in a year. Assuming the dry skimmings are comprised of 100% of zinc oxide, the total weight of the dry skimmings will equal the total weight of the zinc compounds. This assumption was made because the oxygen content in the dry skimmings is not a known quantity that is evaluated. If the oxygen content is known, a more precise amount of zinc oxide could be calculated. Using the above assumption, the zinc oxide in the dry skimmings can be calculated by summing the total amount of dry skimmings generated during the reporting year. Adding both of the example quantities of the zinc oxide and zinc chloride will give the total amount of zinc compounds manufactured as by-products.
Lbs. of Zinc Compounds/yr = (lbs. of ZnO/yr) + (lbs. of ZnCl2/yr or lbs. of ZnSO4/yr)
Further assistance with the estimates may be obtained by referring to the 2001 AGA Form R document. The reporting threshold quantity mandated by CERCLA Section 313 is different from the reportable quantity in CERCLA section 102(a), and the quantities of materials requiring notification under CERCLA sections 311 and 312. For further clarification, the term Reportable Quantity refers to the USEPA Regulation 40 CFR part 302 (CERCLA section 102(a)ii release notification which designates chemicals, and the quantities above which the person must report when released to the environment). The RQ for zinc is 1000 pounds. The RQ for other typical galvanizing zinc compounds (zinc ammonium chloride, zinc chloride, zinc sulfate) is also 1000 pounds. The notification is designated as the responsibility of a person with knowledge.
Please refer to the various state and federal regulations to determine the specific requirements for your facility.
1 AGA Health Safety & Environment Notes for Hot Dip Galvanizing, Updated Form R Calculations, January 2001, Volume 2 Issue 1, Revision 1 July 2001. T.Langill, C.Kleen. i EPCRA: Emergency Planning and Community Right to Know Act, refers to SARA III Section 311, 312, & 313 collectively. The list of chemicals for each section is different. ii CERLCA section 102(a) is regulated under USEPA 40 CFR Part 302-Designation, Reportable Quantities, and Notification. This regulation is enforced in conjunction with other DOT and USEPA regulations
© 2023 American Galvanizers Association. The material provided herein has been developed to provide accurate and authoritative information about after-fabrication hot-dip galvanized steel. This material provides general information only and is not intended as a substitute for competent professional examination and verification as to suitability and applicability. The information provided herein is not intended as a representation or warranty on the part of the AGA. Anyone making use of this information assumes all liability arising from such use.
What happened to the 'detailed guidance document '? Is there also a document / guidance on hydrochloric acid fumes manufactured from the pickling tanks?